Abstract：Pentanol and hexanol has been chosen as biomass reforming oil derived model compounds and aromatized into benzene, toluene and para-xylene (BTX) over ZSM-5, Beta and USY catalysts. It was found that ZSM-5 performed the best among the three catalysts and the aromatic compounds accounted more than 90% in liquid products over ZSM-5. The reaction intermediates that analyzed by quench method indicated that C5-C8 olefins and cycloalkanes were the main reaction intermediates. The controlled intermediates model reactions further demonstrated that pentanol and hexanol underwent the processes of dehydration, cyclization, dehydrogenation and were finally transformed into BTX.
Song Qi,Zheng Junlin,Qi Xiaolan et al. Production of Benzene, Toluene and para-Xylene Light Aromatics fromBiomass Reforming Oil Derived Model Compounds[J]. 化学反应工程与工艺, 2016, 32(4): 307-312.
