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化学反应工程与工艺
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清洁化生产乙苯的分子筛催化剂研究进展
王达锐,金少青,杨 帆,封景耀,刘滢昊,王一棪,孙洪敏,杨为民
中石化(上海)石油化工研究院有限公司,绿色化工与工业催化全国重点实验室,上海 201208
Research Progress in Zeolite Catalysts Applied in the Clean Production of Ethylbenzene
WANG Darui, JIN Shaoqing, YANG Fan, FENG Jingyao, LIU Yinghao, WANG Yiyan, SUN Hongmin, YANG Weimin
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, SINOPEC Shanghai Research Institute of Petrochemical Technology Company Limited, Shanghai 201208, China
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摘要 乙苯作为大宗化工原料应用广泛,目前工业上主要通过分子筛催化苯与乙烯烷基化制得,分子筛催化剂的开发与更新换代对于实现乙苯的绿色低碳高效生产具有重要意义。本文从三个方面综述了用于乙苯生产的分子筛催化剂的研究进展,包括气相法、液相法及其它制备乙苯路线所使用的分子筛催化剂,并总结了分子筛催化剂的活性中心修饰、孔道结构调变及晶体形貌控制在乙苯生产中的应用,指出应基于具体乙苯生产路线的特点,有针对性地对分子筛催化剂在活性中心、水热稳定性、传质性能等方面进行优化。
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作者相关文章
王达锐
金少青
杨 帆
封景耀
刘滢昊
王一棪
孙洪敏
杨为民
关键词 乙苯分子筛活性中心孔道结构晶体形貌    
Abstract:Ethylbenzene is a kind of bulk chemical with numerous usages, which is mainly produced via the zeolite-catalyzed alkylation reaction between benzene and ethylene. Hence, the development and upgrading of zeolite catalysts are of great significance for the green, low-carbon and efficient production of ethylbenzene. This article reviewed the research progress in zeolite catalysts utilized in ethylbenzene production, including the zeolite catalysts in gas-phase ethylbenzene production, the zeolite catalysts in liquid-phase ethylbenzene production, and the zeolite catalysts in other ethylbenzene production routes. The methods for active sites modification, pore-structure adjustment, as well as morphology control applied in ethylbenzene production were summarized, which suggested the optimization of zeolite catalysts should be made based on specified ethylbenzene production route, focusing on the active centers, hydrothermal stability, diffusion capability and other aspects.
Key wordsethylbenzene    zeolites    active centers    pore structure    crystal morphology   
收稿日期: 2024-11-28     
基金资助:上海市科研计划专项经费(22YS1401100)。
作者简介: 王达锐(1990—),男,研究员;杨为民(1966—),男,中国工程院院士,通信联系人,E-mail: yangwm.sshy@sinopec.com。
引用本文:   
王达锐,金少青,杨 帆等. 清洁化生产乙苯的分子筛催化剂研究进展[J]. 化学反应工程与工艺, 2025, 41(1): 44-57.
WANG Darui,JIN Shaoqing,YANG Fan et al. Research Progress in Zeolite Catalysts Applied in the Clean Production of Ethylbenzene[J]. Chemical Reaction Engineering and Technology, 2025, 41(1): 44-57.
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