Kinetics of Thiophene and Benzothiophene Hydrodesulfurization over Co-Mo/γ-Al2O3 Catalyst
1. State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;
2. Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun 113001, China
Abstract：Hydrodesulfurization of thiophene and/or benzothiophene was carried out on Co-Mo/γ-Al2O3 catalyst in an isothermal integral reactor under different reaction temperatures, sulfur-containing compound concentrations and hydrogen sulfide partial pressures. LHHW reaction kinetic equation for hydrodesulfurization of thiophene alone or together with benzothiophene was established. The importance of kinetic study using real composition of raw materials under actual industrial operating conditions has been demonstrated.
Yang Hui 1,Wang Xuehang 1,Duan Xuezhi 1 et al. Kinetics of Thiophene and Benzothiophene Hydrodesulfurization over Co-Mo/γ-Al2O3 Catalyst[J]. 化学反应工程与工艺, 2015, 31(5): 400-406.
