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金属有机骨架材料Fe/Cu-BTC的制备及其脱硫性能
韩 笑，贾银娟，刘 闯，陈 奕，高晓晨，高焕新，王振东
中国石油化工股份有限公司上海石油化工研究院，绿色化工与工业催化国家重点实验室，上海 201208
Preparation and Desulfurization Performance of Metal-Organic Framework Material Fe/Cu-BTC
HAN Xiao, JIA Yinjuan, LIU Chuang, CHEN Yi, GAO Xiaochen, GAO Huanxin, WANG Zhendong
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China
Abstract：The metal-organic framework material Fe/Cu-BTC was prepared by modification of Cu-BTC with FeCl2. The obtained materials were characterized by X ray diffraction (XRD), scanning electron microscope (SEM), X ray energy dispersive spectroscopy (EDS), inductively coupled plasma (ICP), N2 adsorption and X ray photoelectron spectroscopy (XPS). The static adsorption property, removal ratio of sulfide, dynamic adsorption and regeneration property of Fe/Cu-BTC were investigated. The results showed that the reduction of Cu(II) to Cu(I) happened in the Cu-BTC during the modification process of FeCl2 and the corresponding crystallinity decreased after modification with FeCl2 because of over reduction. Besides, with the increase of Fe/Cu molar ratio, the adsorption capacity of the adsorbents Fe/Cu-BTC for 1-propanethiol and ethyl sulfide increased first and then decreased. The sulfur capacity of Fe/Cu-BTC-0.15 with 0.15 molar ratio of Fe to Cu reached the highest level. It’s adsorption capacities for 1-propanethiol and ethyl sulfide were 32.3% and 46.3% higher than those of Cu-BTC respectively, the dynamic adsorption capacities of Fe/Cu-BTC-0.15 for 1-propanethiol and ethyl sulfide were 58.0% and 65.9% higher than those of Cu-BTC. The ratio of adsorption for 1-propanethiol and ethyl sulfide by Fe/Cu-BTC-0.15 were high up to 90.5% and 88.5% in the simulated oil with high sulfur content. The adsorption capacity of the regenerated Fe/Cu-BTC-0.15 for ethyl sulfide reached 91.3% of the fresh one.
HAN Xiao,JIA Yinjuan,LIU Chuang et al. Preparation and Desulfurization Performance of Metal-Organic Framework Material Fe/Cu-BTC[J]. Chemical Reaction Engineering and Technology, 2023, 39(1): 20-28.
