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Mo负载丝光沸石（Mo/MOR）双功能催化剂的表面性质及其加氢裂解性能
中国石油化工股份有限公司上海石油化工研究院，绿色化工与工业催化国家重点实验室，上海 201208
The Surface Properties and Catalytic Activity of Mo/MOR Bifunctional Catalysts in Hydrocracking of Tetralin
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China
Abstract：Mo/MOR series samples with different content of Mo were synthesized and characterized by various techniques. When the content of Mo was below 2%, it was found that with the increasing amount of Mo, the pore structure of zeolites maintained. Mo species was found to locate on acid sites of catalysts, which did not lead to a significant change on the acid amount of catalysts. When the content of Mo was above 2%, it was found that with the increasing amount of Mo, the specific surface area and pore volume of micropores decreased evidently, also Mo species gradually interacted with Lewis and Br?nsted acid sites leading to the loss of acid sites on catalysts. In hydrocracking of tetralin, 2Mo/MOR exhibited the highest conversion and selectivity of hydrocracking reaction, which was owing to the synergistic effect of metal sites and acid sites on catalysts.
WU Yanan,LI Jingqiu,QI Xiaolan et al. The Surface Properties and Catalytic Activity of Mo/MOR Bifunctional Catalysts in Hydrocracking of Tetralin[J]. Chemical Reaction Engineering and Technology, 2022, 38(2): 107-114.
