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Mo负载丝光沸石(Mo/MOR)双功能催化剂的表面性质及其加氢裂解性能
中国石油化工股份有限公司上海石油化工研究院,绿色化工与工业催化国家重点实验室,上海 201208
The Surface Properties and Catalytic Activity of Mo/MOR Bifunctional Catalysts in Hydrocracking of Tetralin
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China
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摘要 以不同金属Mo含量的Mo/MOR系列催化剂为研究对象,结合各类表征手段,发现当Mo含量低于2%(质量分数)时,随金属量上升,分子筛的孔道结构未发生明显的改变,同时Mo物种落位于催化剂表面的酸性位点,造成分子筛酸量略微下降,当Mo含量大于2%时,随金属含量上升,分子筛比表面积和微孔孔容出现明显下降,Mo物种与Lewis酸(L酸)和Br?nsted酸(B酸)位点相互作用,使催化剂表面酸性位点持续流失。在四氢萘加氢裂解反应中,2Mo/MOR具有最优的转化率及加氢裂解反应选择性,这归因于该催化剂表面金属位点和酸性位点间优异的协同作用。
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吴雅楠
李经球
祁晓岚
孔德金
关键词 双功能协同效应四氢萘加氢裂解    
Abstract:Mo/MOR series samples with different content of Mo were synthesized and characterized by various techniques. When the content of Mo was below 2%, it was found that with the increasing amount of Mo, the pore structure of zeolites maintained. Mo species was found to locate on acid sites of catalysts, which did not lead to a significant change on the acid amount of catalysts. When the content of Mo was above 2%, it was found that with the increasing amount of Mo, the specific surface area and pore volume of micropores decreased evidently, also Mo species gradually interacted with Lewis and Br?nsted acid sites leading to the loss of acid sites on catalysts. In hydrocracking of tetralin, 2Mo/MOR exhibited the highest conversion and selectivity of hydrocracking reaction, which was owing to the synergistic effect of metal sites and acid sites on catalysts.
Key wordsmolybdenum    bifunction    synergistic effect    tetralin    hydrocracking   
收稿日期: 2022-01-15     
作者简介: 吴雅楠(1992—),女,博士;孔德金(1965—),男,教授级高级工程师,通讯联系人。E-mail: kongdj.sshy@sinopec.com。
引用本文:   
吴雅楠,李经球,祁晓岚等. Mo负载丝光沸石(Mo/MOR)双功能催化剂的表面性质及其加氢裂解性能[J]. 化学反应工程与工艺, 2022, 38(2): 107-114.
WU Yanan,LI Jingqiu,QI Xiaolan et al. The Surface Properties and Catalytic Activity of Mo/MOR Bifunctional Catalysts in Hydrocracking of Tetralin[J]. Chemical Reaction Engineering and Technology, 2022, 38(2): 107-114.
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