Preparation and Properties of Polyester Modified by Methyl Phenyl Silicone Resin
MENG Fandong1,2, CAO Zheng3, SHEN Yakun1,2, WANG Yixue1,2, QU Yaping3, ZHAN Xiaoli1,2, ZHANG Qinghua1,2
1. Institute of Zhejiang University-Quzhou, Quzhou 324000, China;
2. College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, China;
3. Transfar Zhilian Company Limited, Hangzhou 311215, China
Abstract In view of the problems of poor water resistance, high temperature resistance and weak yellowing resistance of polyester materials, different functional silane monomers were selected to prepare a high-temperature-resistant phenyl silicone resin intermediate through hydrolytic copolymerization in this study. The influence of the ratio of organic groups to silicon atoms on its high-temperature performance was investigated. The intermediate was further used for polyester modification to obtain methyl phenyl silicone-modified polyester, and its structure was confirmed using infrared spectroscopy. The results showed that with an increase in silicone content, the hydrophobic performance of the modified polyester improved, the hardness reached 3H, adhesion improved to grade 0, and the carbon residue at 800 ℃ increases to 39%. Furthermore, the modified polyester coating showed no yellowing after being heat treated at 260 ℃ for 1 h, indicating significant application potential on cookware surfaces such as non-stick pans and air fryers.
MENG Fandong,CAO Zheng,SHEN Yakun et al. Preparation and Properties of Polyester Modified by Methyl Phenyl Silicone Resin[J]. Chemical Reaction Engineering and Technology, 2025, 41(4): 495-502.
MENG Fandong,CAO Zheng,SHEN Yakun et al. Preparation and Properties of Polyester Modified by Methyl Phenyl Silicone Resin[J]. Chemical Reaction Engineering and Technology, 2025, 41(4): 495-502.
